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个人信息

姓名:郭瑞

学历:博士

职称:研究员

E-mailruiguo@ccnu.edu.cn


教育与研究经历

郭瑞1989年出生于山东寿光,现任ok138cn太阳集团529研究员

20233-至今ok138cn太阳集团529ok138cn太阳集团529,研究员,硕士生导师

202012-20233,中国科学院上海有机化学研究所,助理研究员

20189-20209月,美国匹兹堡大学,化学系,博士后,合作导师:Prof. Yiming Wang

20159-20186月,中国科学院上海有机化学研究所,博士,导师:张国柱研究员

20129-20156月,兰州大学,化学化工学院, 硕士,导师:翟宏斌教授

20089-20126,中国海洋大学,医药学院,学士

 

研究领域与兴趣

1.过渡金属催化有机合成方法学

2.自由基介导的碳氢键官能团化反应

3.有机氟化学

4.生物活性分子的合成与功能优化

 

承担项目与课题信息

1.ok138cn太阳集团529高层次人才启动经费,2023.3-2028.3,主持

 

学术成果(代表性论文)

1. Rui Guo, Chao Shu*, Guozhu Zhang*, Photoinduced Metal-free α-C–H Borylation of Aliphatic Amines, Chem, 2022, 8, 2902-2904. (Previews)

2. Rui Guo‡, Haijing Xiao‡, Sijia Li, Yixin Luo, Jiahui Bai, Mengzhen Zhang, Xiaotian Qi*, Yinlong Guo*, Guozhu Zhang*, “Photoinduced Copper-Catalyzed Asymmetric C(sp3)-H Alkynylation of Cyclic Amines by Intramolecular 1,5-Hydrogen Atom Transfer”, Angew. Chem. Int. Ed., 2022, 61, e202208232. (: contributed equally)

3. Rui Guo‡, Xiaotian Qi‡, Hengye Xiang, Paul Geaneotes, Ruihan Wang, Peng Liu*and Yi-Ming Wang*, “Stereodivergent Alkyne Hydrofluorination Using Protic Tetrafluoroborates as Tunable Reagents” Angew. Chem. Int. Ed., 2020, 59, 16651−16660. (: contributed equally) 

4. Rui Guo and Guozhu Zhang*, “Expedient Synthesis of 1,5-Diketones by Rhodium-Catalyzed Hydroacylation Enabled by C−C Bond Cleavage” J. Am. Chem. Soc., 2017, 139, 12891−12894. 

5. Rui Guo‡, Xinxin Zheng‡, Dayong Zhang*, Guozhu Zhang*, “Rhodium(I)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp3)–C(sp3) bond cleavage” Chem. Sci., 2017, 8, 3002−3006. (: contributed equally) 

6. Rui Guo, Xueling Mo, Guozhu Zhang*, “Synthesis of 2-(2-Oxo-2-phenylethyl)cyclopentanone by Rhodium-Catalyzed Tandem Alkynyl Cyclobutanols Hydroacylation and Semipinacol Rearrangement” Org. Lett., 2019, 21, 1263−1267.

7. James C. Corcoran‡, Rui Guo‡, Yue Xia, and Yi-Ming Wang*, “Vinyl Cation-Mediated Intramolecular Hydroarylation of Alkynes Using Pyridinium Reagents”, Chem. Commun. 2022, 58, 11523-11526. (:contributed equally) 

8. Rui Guo‡, Jiale Sang‡, Haijing Xiao, Junxia Li and Guozhu Zhang*, “Development of Novel Phosphino-Oxazoline Ligands and Their Application in Asymmetric Alkynlylation of Benzylic Halides” Chin. J. Chem. 2022, 40, 1337−1345. (: contributed equally) 

9. Rui Guo, Hongbin Zhai, Yun Li*, “Synthetic studies on pseudolaric acid B: enantioselective synthesis of C4,C10-di-epi-trans-fused [5-7]-bicyclic skeleton” Chin. Chem. Lett., 2021, 32 1400−1402. 

10. Rui Guo‡, Qin Yang‡, Qinshan Tian, Guozhu Zhang*, “Barbier-type anti-Diastereo-and Enantioselective Synthesis of β-Trimethylsilyl, Fluorinated Methyl, Phenylthio Homoallylic Alcohols” Sci. Rep., 2017, 7, 4873. (: contributed equally) 

 

获奖及荣誉信息

中国化学会第三届全国有机自由基化学会议优秀墙2022

中国化学会第31届学术年会优秀墙报2018

中国科学院三好学生(2017

中国海洋大学优秀毕业生(2012